This dissertation develops strategies for fabricating high-performance, low-temperature processed indium oxide thin-film transistors for monolithic 3D integration, achieving record mobility and stability through optimized annealing, passivation, and channel engineering techniques.

Biography

Na Xiao is a Ph.D. candidate in Electrical and Computer Engineering at King Abdullah University of Science and Technology (KAUST), under the supervision of Professor Xiaohang Li. She earned her M.S. degree in Chemistry from Soochow University at Institute of Functional Nano & Soft Materials (FUNSOM)  in 2018.

Research Interests

Na Xiao's research focuses on semiconductor fabrication, semiconductor materials and devices, oxide semiconductors, and nanoscale device technologies, and characterization of wide band gap materials.

About

The continuous scaling of silicon complementary metal-oxide semiconductor (CMOS) transistors has driven significant technological advancements, enabling denser, faster, and more cost-effective integrated circuits. However, as technology nodes shrink below 10 nm, further progress in three-dimensional (3D) scaling of transistors faces substantial challenges, including increased process complexity and additional manufacturing steps. Additionally, the concurrent scaling of interconnects exacerbates parasitic resistance and capacitance, leading to reduced signal bandwidth and increased power consumption. To overcome these limitations, three-dimensional (3D) integration technology has emerged as a promising alternative.

Monolithic 3D integration (M3DI), which involves fabricating transistors in the back-end-of-line (BEOL), offers unique advantages, including cost-effective processes and ultrahigh-density interconnecting-vias (>107/mm2). However, fabricating high-performance BEOL-compatible transistors within a strict thermal budget (<400 °C) remains a critical challenge. Oxide semiconductors (OSs) have emerged as promising materials for BEOL-compatible transistors due to their high mobility, extremely low leakage current, low-temperature processing capabilities, and large-area scalability.

This dissertation explores strategies for developing high-mobility BEOL-compatible indium oxide (In2O3) thin-film transistors (TFTs) for M3DI. First, a BEOL-compatible process was established to achieve high field-effect mobility (μFE >40 cm2V−1s−1) In2O3 TFTs through a straightforward post-annealing method. The influence of annealing on the electrical performance of sputtered In2O3 TFTs was studied, with a focus on changes in oxygen-related species in the In2O3 channel.

Next, a novel approach combining a sputtered Al2O3 passivation layer with O2 plasma pretreatment was developed to enhance mobility and stability of In2O3 TFTs. This method resulted in devices with a record-high μFE of 128.3 cm2V−1s−1 at a low thermal budget of 200 °C, along with excellent bias stability among passivated OS TFTs.

Furthermore, enhancement-mode In2O3 TFTs with recessed-channel structures were demonstrated using a dry etching process for precise channel thickness engineering. These devices exhibited a high µFE of 55.6 cm2V−1s−1 at an overall process temperature of 200 °C, establishing a new benchmark for sputtered OS TFTs.

Lastly, temperature-dependent electron transport in In2O3 TFTs was analyzed down to a cryogenic temperature of 2 K. Benchmarking revealed that the developed BEOL-compatible In2O3 TFTs achieved the highest µFE of 43 cm2V−1s−1 at cryogenic temperatures among all reported OS TFTs.

Education

Master of Science (M.S.)
Chemistry, Soochow University, China, 2018